Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

Anhydrous Tin Tetrachloride

TinStar™ Anhydrous SnCl₄ Grade-A is a colorless, fuming liquid with high purity (≥99.99%), used as a catalyst in polymerization and PVC stabilization. It reacts vigorously with water, requiring strict anhydrous handling. Key features include low metallic impurities, excellent volatility, and consistent batch-to-batch performance for electronic chemical and fine synthesis applications.
  • anhydrous tin tetrachloride_24fb4587
  • anhydrous tin tetrachloride_24fb4587

Features Of Anhydrous Tin Tetrachloride

  1. High-purity anhydrous formulation (>99.9% assay) ensures minimal water interference in moisture-sensitive reactions.

  2. Strong Lewis acidity enables efficient catalysis in Friedel–Crafts acylations and esterifications.

  3. Low boiling point (114 °C) facilitates easy removal post-reaction via distillation under mild conditions.

  4. Non-oxidizing nature preserves sensitive functional groups during metal-mediated syntheses.

  5. Consistent batch-to-batch performance certified with full traceability and CoA documentation.

Typical Applications Of Anhydrous Tin Tetrachloride

  1. Catalyst for the synthesis of organotin compounds, including vinyltin and allyltin reagents used in Stille coupling.

  2. Reagent in the preparation of tin oxide (SnO₂) thin films via chemical vapor deposition (CVD) for transparent conductive coatings.

  3. Dehydrating agent in the production of high-molecular-weight polyesters and polycarbonates.

  4. Intermediate in the manufacture of flame-retardant additives and PVC stabilizers.

  5. Etchant and dopant precursor in semiconductor fabrication processes requiring precise tin incorporation.

Specifications Of Anhydrous Tin Tetrachloride



Chemical TypeInorganic tin(IV) halide
Product FormLiquid (clear, colorless to pale yellow)
AppearanceClear, fuming liquid with pungent odor
Melting Point−33 °C
Boiling Point114 °C at 760 mmHg
Density (20 °C)2.226 g/cm³
Assay (by titration)≥99.9% SnCl₄
Water Content (KF)≤50 ppm


Compatible Systems Of Anhydrous Tin Tetrachloride

Common Compatible SystemsSuitability
Anhydrous chlorinated solvents (e.g., CH₂Cl₂, CCl₄)Highly Recommended – Stable, non-reactive dissolution medium for catalytic use
Organic acid anhydrides (e.g., acetic anhydride)Recommended – Compatible as co-reagent in acylation systems
Alkyl/aryl chlorides (e.g., benzyl chloride)Suitable – Reacts controllably under stoichiometric conditions
Stainless steel (316 SS) and glass-lined reactorsHighly Recommended – Corrosion-resistant handling at ambient temperatures

Anhydrous Tin Tetrachloride – Frequently Asked Questions (FAQ)

Q1: What is the CAS Number for Anhydrous Tin Tetrachloride?

A: The CAS Registry Number is 7646-78-8.


Q2: How should Anhydrous Tin Tetrachloride be handled to prevent hydrolysis during storage or transfer?

A: Store under inert atmosphere (N₂ or Ar) in sealed, moisture-proof containers; use dry-gas purged syringes or cannula techniques for transfer; avoid exposure to ambient humidity above 30% RH.


Q3: How does Anhydrous Tin Tetrachloride compare to Titanium Tetrachloride (TiCl₄) as a Lewis acid catalyst?

A: SnCl₄ exhibits milder Lewis acidity than TiCl₄, offering better functional group tolerance and reduced risk of substrate decomposition; it also demonstrates superior selectivity in asymmetric aldol-type reactions when paired with chiral ligands.


Q4: Is Anhydrous Tin Tetrachloride compliant with REACH and RoHS regulations?

A: Yes — supplied with full REACH registration (EU No. 01-2119458032-42-XXXX) and RoHS-compliant documentation; contains no SVHC substances above threshold levels per current Annex XIV.



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