Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

Dow DEN 431 Phenolic Epoxy Resin

Dow DEN 431 Phenolic Epoxy Resin is a high-performance brominated novolac epoxy resin from Dow’s DEN series, offering exceptional flame retardancy, thermal stability, and chemical resistance. Widely used in printed circuit boards, encapsulants, and aerospace composites, it delivers superior dielectric properties and low moisture absorption versus standard epoxies.
  • dow den 431 phenolic epoxy resin_7a44236b
  • dow den 431 phenolic epoxy resin_7a44236b

Features Of Dow DEN 431 Phenolic Epoxy Resin

  1. High functionality phenolic epoxy resin with multiple epoxide groups per molecule for enhanced crosslink density.

  2. Excellent thermal stability and char yield, supporting performance in elevated-temperature environments.

  3. Superior chemical resistance—particularly to acids, alkalis, and solvents—after full cure.

  4. Low viscosity relative to other high-functionality phenolic epoxies, enabling improved processability and filler loading.

  5. Designed for compatibility with conventional amine and anhydride curing agents used in high-performance composites and encapsulants.

Typical Applications Of Dow DEN 431 Phenolic Epoxy Resin

  1. Aerospace composite matrices requiring flame, smoke, and toxicity (FST) compliance.

  2. Electrical encapsulation and potting compounds for high-voltage power electronics.

  3. High-performance adhesives in structural bonding of metal and composite substrates.

  4. Carbon fiber prepregs for defense and industrial tooling applications.

  5. Fire-resistant printed circuit board (PCB) laminates and bonding films.

Specifications Of Dow DEN 431 Phenolic Epoxy Resin

Chemical TypePhenolic epoxy novolac resin
Product FormOff-white to light tan solid flakes or powder
AppearanceFree-flowing crystalline solid
Epoxy Equivalent Weight (EEW)170–190 g/eq
Softening Point85–95 °C
Functionality (Average Epoxide Groups per Molecule)≥ 4.0
Volatiles Content< 0.5 wt%
Primary ApplicationsHigh-temperature composites, electrical insulation, fire-safe laminates


Dow DEN 431 Phenolic Epoxy Resin – Frequently Asked Questions (FAQ)

Q1: What distinguishes DEN 431 from standard bisphenol-A epoxy resins?

A: DEN 431 is a novolac-type phenolic epoxy resin, offering significantly higher functionality and aromatic content than conventional bisphenol-A epoxies. This results in enhanced thermal stability, improved chemical resistance—especially to strong acids and solvents—and superior char formation at elevated temperatures.


Q2: Is DEN 431 suitable for high-temperature curing applications?

A: Yes—DEN 431 is specifically designed for high-performance thermoset systems requiring elevated cure temperatures (typically above 150 °C). Its phenolic novolac backbone enables robust crosslinking with amine or anhydride hardeners, yielding matrices with excellent retention of mechanical properties under prolonged thermal stress.


Q3: How does DEN 431 perform in flame-retardant composite formulations?

A: Due to its high aromatic density and char-forming tendency, DEN 431 contributes inherent flame resistance and reduced heat release in cured composites. It is often selected as a base resin in aerospace, electronics encapsulation, and industrial linings where low smoke and high limiting oxygen index (LOI) are critical design criteria.


Q4: Can DEN 431 be blended with other epoxy resins to modify performance?

A: Yes—DEN 431 is commonly blended with lower-functionality epoxies (e.g., DGEBA or hydrogenated bisphenol-A types) to balance reactivity, toughness, and thermal performance. Blending allows formulators to tailor glass transition temperature, viscosity, and crosslink density without compromising essential high-temperature integrity.



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