Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

Methylbenzotriazole TTA

Methylbenzotriazole TTA is a high-performance corrosion inhibitor from the BTA series by ACME Chemicals, specifically formulated as 1-methyl-1H-benzotriazole for copper and copper-alloy protection in cooling systems, antifreeze formulations, and metalworking fluids—offering superior thermal stability, low volatility, and enhanced film-forming capability versus standard benzotriazole.
  • methylbenzotriazole tta_7b3fdb45
  • methylbenzotriazole tta_7b3fdb45

Features Of Methylbenzotriazole TTA

  1. Highly effective copper corrosion inhibitor with strong chemisorption on copper and copper alloy surfaces.

  2. Thermally stable up to 250 °C, maintaining performance in high-temperature coolant and heat transfer systems.

  3. Low volatility and minimal water solubility ensure long-term persistence in closed-loop industrial fluids.

  4. Non-oxidizing and non-foaming—compatible with common antifreeze glycols (EG/PG) and synthetic base stocks.

  5. Readily dispersible in organic solvents and formulated lubricants without requiring co-solvents or surfactants.

Typical Applications Of Methylbenzotriazole TTA

  1. Corrosion protection additive in automotive and heavy-duty engine coolants (OAT and HOAT formulations).

  2. Stabilizer in copper-containing heat exchanger fluids for HVAC and district heating systems.

  3. Functional component in metalworking fluid concentrates targeting copper-rich machining alloys (e.g., brass, beryllium copper).

  4. Additive in transformer oils and dielectric fluids where copper conductor protection is critical.

  5. Performance enhancer in industrial closed-loop recirculating water systems with mixed-metal piping (Cu, Fe, Al, stainless steel).

Specifications Of Methylbenzotriazole TTA



Chemical TypeBenzotriazole derivative (1-methyl-1H-benzotriazole)
Product FormOff-white to light tan crystalline powder
AppearanceFree-flowing microcrystalline solid
Melting Point84–87 °C (determined by DSC)
Primary ApplicationsCopper corrosion inhibition in aqueous and semi-aqueous industrial fluids
Key FeaturesAdsorbs rapidly on copper; forms protective monolayer film; pH-stable across 5.5–10.5
BenefitsReduces copper leaching by >95% vs. untreated controls; extends system service life; low odor
Regulatory ComplianceREACH registered; compliant with EU Directive 2004/42/EC (VOC limits); not classified under CLP


Compatible Systems Of Methylbenzotriazole TTA

Common Compatible SystemsSuitability
Ethylene Glycol/Water Coolants (OAT/HOAT)Highly Recommended – Excellent stability and synergistic inhibition with sebacates/molybdates
Polyglycol-Based Metalworking FluidsRecommended – Effective at 0.1–0.3 wt%; no adverse interaction with EP additives
Alkaline Aqueous Cleaning Solutions (pH 9–11)Suitable – Maintains inhibitory activity during short-term immersion; may require pH buffering
Mineral Oil & PAO Transformer OilsHighly Recommended – Soluble up to 0.5 wt%; enhances copper passivation without affecting dielectric strength

Methylbenzotriazole TTA – Frequently Asked Questions (FAQ)

Q1: What is the CAS Number for Methylbenzotriazole TTA?

A: The CAS Registry Number is 29385-43-1 (1-Methyl-1H-benzotriazole).


Q2: What is the recommended dosage range in coolant formulations?

A: Typical use level is 0.05–0.25 wt% active in final concentrate; optimal performance is observed at ≥0.15 wt% in ethylene glycol/water blends.


Q3: How does Methylbenzotriazole TTA compare to standard benzotriazole (BTA) in terms of migration resistance?

A: The N-methyl substitution reduces polarity and increases hydrophobicity, resulting in significantly lower leaching from treated surfaces in dynamic flow conditions and reduced extractability in aqueous rinse tests.


Q4: Is Methylbenzotriazole TTA approved for use in potable water contact applications?

A: No—this product is not NSF/ANSI 60 or 61 certified and is not intended for drinking water systems. It is formulated exclusively for industrial closed-loop and non-potable applications.



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