Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

EM Resist HSQ 22% Photosensitive Adhesive

EM Resist HSQ 22% is a high-resolution, silicon-based photosensitive adhesive from the EM Resist series by Electron Microscopy Sciences. Designed for e-beam and deep-UV lithography, it offers exceptional line fidelity, thermal stability up to 1000°C, and low outgassing—ideal for MEMS, nanofabrication, and hard mask applications in advanced semiconductor processes.
  • em resist hsq 22 photosensitive adhesive_851e86ae
  • em resist hsq 22 photosensitive adhesive_851e86ae

Features Of EM Resist HSQ 22% Photosensitive Adhesive

  1. High-resolution negative-tone imaging capability with sub-10 nm feature definition in e-beam lithography.

  2. Excellent thermal stability up to 1000 °C in inert atmospheres, enabling high-temperature etch and release processes.

  3. Low outgassing profile suitable for vacuum-compatible MEMS and nanofabrication environments.

  4. Water-developable formulation eliminates need for organic solvents, enhancing workplace safety and environmental compliance.

  5. Consistent 22 wt% solid content ensures reproducible film thickness control across spin-coating processes (e.g., 100–300 nm at 3000–5000 rpm).

Typical Applications Of EM Resist HSQ 22% Photosensitive Adhesive

  1. Nanoscale mask fabrication for extreme ultraviolet (EUV) and electron-beam lithography.

  2. High-aspect-ratio nanostructure patterning in silicon carbide (SiC), gallium nitride (GaN), and quartz substrates.

  3. Release layer and sacrificial template in MEMS/NEMS device fabrication and nanoimprint stamping.

  4. Direct-write nanolithography for quantum device prototyping and plasmonic metasurface fabrication.

  5. Hard mask application in deep reactive ion etching (DRIE) of silicon and compound semiconductors.

Specifications Of EM Resist HSQ 22% Photosensitive Adhesive



Chemical TypeHydrogen Silsesquioxane (HSQ) based negative-tone photoresist
Product FormLiquid solution in methyl isobutyl ketone (MIBK)
AppearanceClear, colorless to pale yellow liquid
Solid Content22 ± 0.5 wt%
Viscosity (25 °C)4.5–5.5 cP
Primary ApplicationsE-beam lithography, high-resolution hard mask, nanoscale templating
Key FeaturesElectron-sensitive, inorganic silica network after curing, high etch resistance
Regulatory ComplianceREACH compliant; RoHS 2015/863 Annex II compliant; no SVHCs above threshold


Compatible Systems Of EM Resist HSQ 22% Photosensitive Adhesive

Common Compatible SystemsSuitability
JEOL JSM & JEM series e-beam writers (e.g., JSM-7900F, JEM-ARM300F)Highly Recommended – Optimized sensitivity at 100 keV; validated dose range: 100–1000 μC/cm²
Canon FPA-1200NZ2C (EUV scanner with resist underlayer)Recommended – Requires HMDS priming and optimized PAB/PEB; used as EUV hard mask stack component
Spin coaters (Laurell WS-650, Headway EC301)Highly Recommended – Compatible with standard 4″–8″ wafer chucks and MIBK-wet cleaning protocols
Plasma etch systems (Oxford Instruments ICP-RIE, STS Multiplex)Highly Recommended – Demonstrates >15:1 selectivity over Si in SF₆/O₂ chemistries

EM Resist HSQ 22% Photosensitive Adhesive – Frequently Asked Questions (FAQ)

Q1: What is the CAS Number for EM Resist HSQ 22%?

A: The base HSQ polymer component has CAS No. 33999-44-7; the full formulated product (including MIBK solvent) is assigned proprietary batch-specific registration per REACH Annex VI requirements.


Q2: What is the recommended spin-coating speed and post-apply bake (PAB) condition?

A: For 200 nm nominal thickness on Si wafers: spin at 4000 rpm for 30 s; PAB at 90 °C for 90 s on a hotplate with nitrogen purge. Avoid prolonged ambient exposure pre-bake to prevent moisture uptake.


Q3: How does EM Resist HSQ 22% compare to XR-1541 or Dow Corning® HSQ-26?

A: EM Resist HSQ 22% offers tighter molecular weight distribution and lower metal ion contamination (<1 ppb Na/K/Ca) than legacy HSQ formulations, resulting in improved pattern fidelity and reduced defect density in <20 nm features.


Q4: Is extraction or migration of components into process fluids a concern during wet development?

A: No measurable leaching occurs during standard deionized water development (2 min agitation, 23 °C). Residual organics are fully removed in the initial rinse; cured HSQ forms an inert, non-soluble silica network.



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