Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

Photoresist Raw Material Acrylic Acid

Dow Chemical’s Elektron™ AA-100 Acrylic Acid is a high-purity monomer used in photoresist synthesis for semiconductor lithography. Featuring low metal impurities and consistent reactivity, it enables precise polymer backbone formation in positive-tone resists. Ideal for advanced node fabrication (≤7nm), it ensures excellent resolution, adhesion, and etch resistance. Supplied in sealed stainless-steel drums under nitrogen to maintain stability and purity.
  • photoresist raw material acrylic acid_9fbb9e09
  • photoresist raw material acrylic acid_9fbb9e09

Features Of Photoresist Raw Material Acrylic Acid

  1. High-purity monomer with ≥99.5% assay, minimizing residue-induced defects in photolithographic patterning.

  2. Low inhibitor content (MEHQ ≤10 ppm) ensures optimal polymerization control during resist formulation.

  3. Consistent batch-to-batch reactivity and molecular weight distribution for reproducible photoresist performance.

  4. Ultra-low ionic impurities (Na⁺, K⁺, Cl⁻ < 1 ppm each) critical for semiconductor-grade cleanroom compatibility.

  5. Stabilized for long-term storage under refrigerated, nitrogen-blanketed conditions without significant dimerization.

Typical Applications Of Photoresist Raw Material Acrylic Acid

  1. Core monomer in positive-tone acrylic-based photoresists for advanced semiconductor lithography (i-line, KrF, ArF).

  2. Functional comonomer in chemically amplified resists (CARs) to modulate dissolution rate and contrast.

  3. Building block for poly(acrylic acid)-based resin matrices used in display manufacturing (LCD/OLED color filter patterning).

  4. Reactive component in UV-curable photoresist formulations for MEMS and microfluidic device fabrication.

  5. Intermediate in synthesis of acrylic ester derivatives (e.g., tert-butyl acrylate) for protected resist polymers.

Specifications Of Photoresist Raw Material Acrylic Acid



Chemical TypeUnsaturated carboxylic acid monomer
Product FormLiquid (inhibitor-stabilized)
AppearanceClear, colorless to pale yellow liquid
Melting Point13–14 °C
Boiling Point (at 760 mmHg)141 °C
Primary ApplicationsPhotoresist polymer synthesis, acrylic copolymer backbone
Key FeaturesHigh reactivity, low volatility residual, semiconductor-grade purity
Regulatory ComplianceREACH registered; RoHS compliant; non-REACH SVHC candidate (as of latest update)


Compatible Systems Of Photoresist Raw Material Acrylic Acid

Common Compatible SystemsSuitability
KrF Excimer Laser Lithography SystemsHighly Recommended – Excellent transparency at 248 nm and controlled acid-catalyzed deprotection kinetics
ArF Immersion Lithography PlatformsRecommended – Requires co-monomer blending (e.g., with hydroxystyrene) to enhance etch resistance
UV-Curable Inkjet Resist Deposition SystemsSuitable – Compatible with cationic/photoinitiator blends for low-temperature patterning
Spin-Coating Resist Formulation Lines (Semiconductor Fab)Highly Recommended – Fully compatible with standard solvent systems (PGMEA, EL, cyclohexanone)

Photoresist Raw Material Acrylic Acid – Frequently Asked Questions (FAQ)

Q1: What is the CAS Registry Number for this grade of acrylic acid?

A: The CAS number is 79-10-7. This refers specifically to the high-purity, inhibitor-stabilized grade certified for photoresist synthesis.


Q2: What is the typical recommended loading level of acrylic acid in a photoresist polymer formulation?

A: Loading typically ranges from 20–45 mol% in terpolymer systems (e.g., with maleic anhydride and styrene derivatives), optimized per dissolution inhibition profile and lithographic resolution requirements.


Q3: How does this acrylic acid grade differ from technical-grade acrylic acid in resist applications?

A: Technical-grade acrylic acid contains higher levels of aldehydes, heavy metals, and dimer impurities that cause scumming, linewidth variation, and post-exposure bake instability — unsuitable for sub-100 nm lithography.


Q4: Are there documented extraction or migration studies for acrylic acid residues in final semiconductor devices?

A: Yes — validated IC-MS and TOF-SIMS data confirm residual acrylic acid monomer is fully consumed during polymerization and post-apply bake (PAB); no detectable leaching observed after full process integration (detection limit: <0.05 ppb).



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