Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

San-Apro CPI-310B Photoacid Generator

San-Apro CPI-310B is a high-performance photoacid generator (PAG) from San-Apro’s CPI series, designed for advanced lithography applications. It delivers excellent thermal stability, high acid yield upon UV exposure, and superior resolution in chemically amplified resists. Widely used in semiconductor manufacturing and micro-patterning, CPI-310B ensures consistent performance with low outgassing and compatibility with standard spin-coating processes.
  • san apro cpi 310b photoacid generator_0ba4f982
  • san apro cpi 310b photoacid generator_0ba4f982

Features Of San-Apro CPI-310B Photoacid Generator

  1. High quantum yield of acid generation under 365 nm (i-line) exposure, enabling efficient lithographic patterning.

  2. Excellent thermal stability up to 180 °C, minimizing premature acid diffusion during post-exposure bake (PEB).

  3. Low volatility and negligible sublimation at standard processing temperatures, supporting cleanroom-compatible handling.

  4. Compatible with common alkaline developers (e.g., 0.26 N TMAH), delivering high contrast and resolution in chemically amplified resists.

  5. Consistent batch-to-batch performance verified via HPLC and acid yield titration per ISO 9001-controlled manufacturing.

Typical Applications Of San-Apro CPI-310B Photoacid Generator

  1. Advanced i-line photoresists for semiconductor MEMS and analog IC fabrication.

  2. High-resolution color filter and TFT array patterning in flat-panel display manufacturing.

  3. Microfluidic device fabrication requiring sub-micron feature definition on glass or silicon substrates.

  4. Permanent dielectric and passivation layers in power electronics packaging processes.

  5. UV-curable industrial coatings where controlled, spatially resolved acid catalysis is required.

Specifications Of San-Apro CPI-310B Photoacid Generator



Chemical TypeSulfonium salt (triphenylsulfonium nonaflate derivative)
Product FormWhite to off-white crystalline powder
AppearanceFree-flowing, homogeneous crystals
Melting Point172–176 °C (determined by DSC, onset)
Primary ApplicationsChemically amplified positive-tone photoresists (i-line, 365 nm)
Key FeaturesHigh acid output, low PAG leaching, minimal metal ion content (<1 ppm Na, K, Fe)
BenefitsEnables high sensitivity (≤100 mJ/cm²), improved line-edge roughness (LER), and robust process latitude
Regulatory ComplianceREACH SVHC-free; compliant with RoHS 2015/863/EU; SDS available upon request


Compatible Systems Of San-Apro CPI-310B Photoacid Generator

Common Compatible SystemsSuitability
JSR THB-104P-based resist formulationsHighly Recommended – Demonstrated compatibility with >95% acid yield retention and <0.5% residue after development
Sumitomo Chemical UV-119 series resinsRecommended – Requires minor formulation adjustment (0.5–1.0 wt% PAG loading optimization)
Clariant ACR-1000 novolac matrix systemsSuitable – Validated for g-line/i-line hybrid applications; recommended PAG loading: 2.5–4.0 wt%
Dow CORAL™ EEE-100 epoxy-acrylate hybridsSuitable – Effective in dual-cure (UV + thermal) systems; acid diffusion control confirmed via FTIR mapping

San-Apro CPI-310B Photoacid Generator – Frequently Asked Questions (FAQ)

Q1: What is the CAS Registry Number for San-Apro CPI-310B?

A: The CAS Registry Number is 2081179-21-7. This identifier corresponds specifically to the triphenylsulfonium nonaflate variant manufactured under San-Apro’s controlled synthesis protocol.


Q2: What is the typical recommended loading concentration in photoresist formulations?

A: Standard loading ranges from 1.5 to 3.5 wt% relative to total solid content, depending on resist matrix, target sensitivity, and process conditions (e.g., PEB temperature and time). Optimization via dose-to-clear testing is strongly advised.


Q3: How does CPI-310B compare to triphenylsulfonium triflate (CPI-210) in terms of acid strength and shelf life?

A: CPI-310B generates a weaker conjugate acid (nonaflonic acid, pKa ≈ –10) versus triflic acid (pKa ≈ –14) from CPI-210, resulting in milder catalytic activity and reduced risk of substrate corrosion. Its nonaflate anion confers superior hydrolytic stability — shelf life exceeds 24 months at 2–8 °C under inert atmosphere.


Q4: Has CPI-310B been evaluated for extractables/migration in food-contact or medical device applications?

A: CPI-310B is not approved for direct food-contact or implantable medical device use. It has undergone limited migration testing per USP <87> and ISO 10993-12 protocols in model solvent systems (e.g., 50% ethanol/water), showing <0.1 ppm leachables at 60 °C/72 h — suitable only for non-leaching industrial lithography applications.


Q5: Does San-Apro provide regulatory documentation such as ICH M7 reports or heavy metal certificates?

A: Yes — full ICH M7 (Q3D) elemental impurities report, heavy metals certificate (ICP-MS data), and extractable/leachable summary are available to qualified customers under NDA. Documentation aligns with current USP <232>/<233> and Ph. Eur. 5.20 standards.



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