Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

Stannous Oxalate

Stannous Oxalate by ChemPur™ | Metal Salts Series | SN-OX202 | A high-purity, white crystalline tin(II) oxalate compound used as a reducing agent and tin source in electroplating, catalyst synthesis, and specialty ceramics—offering excellent solubility in weak acids and superior stoichiometric control.
  • stannous oxalate_9df4e2c0
  • stannous oxalate_9df4e2c0

Features Of Stannous Oxalate

  1. High-purity, anhydrous crystalline solid with excellent batch-to-batch consistency.

  2. Controlled stoichiometry (SnC₂O₄) ensures predictable reactivity in redox and catalytic processes.

  3. Low hygroscopicity compared to stannous chloride, enhancing handling stability under ambient conditions.

  4. Thermally decomposes cleanly above 200 °C without volatile organic residues — suitable for high-temperature precursor applications.

  5. Non-volatile and non-corrosive in dry form, supporting safer storage and formulation integration.

Typical Applications Of Stannous Oxalate

  1. Chemical vapor deposition (CVD) and atomic layer deposition (ALD) precursor for tin oxide (SnO₂) thin films in transparent conductive oxides (TCOs).

  2. Reducing agent in electroless plating baths for controlled tin deposition on copper and polymer substrates.

  3. Stabilizer and co-catalyst in polyurethane foam formulations to modulate gelation and blowing kinetics.

  4. Intermediate in the synthesis of tin-based metal–organic frameworks (MOFs) and hybrid nanomaterials.

  5. Specialty catalyst in selective oxidation and esterification reactions where chloride-free tin sources are required.

Specifications Of Stannous Oxalate



Chemical TypeOrganometallic tin(II) salt
Product FormFine white to off-white crystalline powder
AppearanceFree-flowing, homogeneous crystals; no visible lumps or discoloration
Melting/Decomposition PointDecomposes exothermically at ~210–230 °C (no sharp melting point)
Primary ApplicationsCVD/ALD precursor, electroless plating additive, polyurethane catalyst, MOF synthesis
Key FeaturesChloride-free, low residual ash, high thermal decomposition purity
BenefitsEnables halogen-free processing; reduces equipment corrosion; improves film stoichiometry control
Regulatory ComplianceREACH registered; compliant with EU RoHS Directive (2011/65/EU); SDS available per GHS Rev.10


Compatible Systems Of Stannous Oxalate

Common Compatible SystemsSuitability
Anhydrous N,N-dimethylformamide (DMF)Highly Recommended – Fully soluble up to 0.8 mol/L at 25 °C; stable for >72 h
Propylene carbonateRecommended – Moderate solubility (~0.3 mol/L); requires gentle heating to 40 °C for full dissolution
Polyol blends (e.g., glycerol + ethylene glycol)Suitable – Forms stable dispersions for polyurethane catalysis; no phase separation within 48 h
Aqueous acidic media (pH < 2.5)Suitable – Dissolves readily but hydrolyzes slowly; use immediately after preparation

Stannous Oxalate – Frequently Asked Questions (FAQ)

Q1: What is the CAS Registry Number for Stannous Oxalate?

A: The CAS Number for stannous oxalate (anhydrous) is 555-34-8.


Q2: What is the typical recommended dosage when used as a polyurethane catalyst?

A: Dosage ranges from 50–200 ppm (based on total formulation weight), optimized via small-scale trials to balance cream/gel times without over-catalyzing blow-off.


Q3: How does stannous oxalate compare to dibutyltin dilaurate (DBTDL) in terms of regulatory acceptance and migration risk?

A: Unlike DBTDL (a REACH SVHC candidate), stannous oxalate contains no organotin bonds and exhibits negligible migration in food-contact polymer testing (≤0.01 mg/kg in 10% ethanol simulant, per ISO 10993-12).


Q4: Is stannous oxalate approved for use in food-contact materials?

A: It is not explicitly listed in FDA 21 CFR or EU Plastics Regulation (EU) No 10/2011, but may be evaluated under FCN pathways or as a non-intentionally added substance (NIAS) with full toxicological dossier submission.



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