Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

Tetrabutyltin

Tetrabutyltin (TBT) is a colorless liquid organotin compound widely used as a catalyst in silicone curing and PVC stabilizer. Brand: Gelest; Series: Metal-Organic; Model: TBT-100; Core term: tetrabutyltin. It exhibits high thermal stability and reactivity in transesterification and condensation reactions. Handle with care due to toxicity and environmental persistence. Complies with REACH guidelines for controlled industrial use.
  • tetrabutyltin_15c6305d
  • tetrabutyltin_15c6305d

Features Of Tetrabutyltin

  1. Highly effective organotin catalyst for esterification and transesterification reactions.

  2. Thermally stable up to 200 °C, enabling use in high-temperature polymerization processes.

  3. Low volatility compared to smaller alkyltin compounds, supporting safer handling and reduced atmospheric loss.

  4. Excellent solubility in common organic solvents including toluene, xylene, and chlorinated hydrocarbons.

  5. Precise stoichiometric control due to well-defined molecular structure and high purity availability.

Typical Applications Of Tetrabutyltin

  1. Catalyst in the synthesis of polyesters and alkyd resins for coatings and inks.

  2. Key reagent in the preparation of tin-based stabilizers for PVC processing.

  3. Intermediate in the production of specialty organotin compounds for agrochemicals and biocides.

  4. Facilitator in silicone crosslinking systems requiring delayed cure profiles.

  5. Model compound in analytical method development for organotin residue testing (e.g., food contact materials).

Specifications Of Tetrabutyltin



Chemical TypeOrganotin compound / Tetraalkyltin
Product FormLiquid (clear, colorless to pale yellow)
AppearanceClear, mobile liquid with mild characteristic odor
Melting Point−79 °C
Boiling Point220–225 °C at 760 mmHg
Density (20 °C)1.005–1.015 g/cm³
Purity (GC)≥ 98.0%
Regulatory ComplianceREACH registered; not listed under EU Biocidal Products Regulation (BPR) Annex I for active substance status


Compatible Systems Of Tetrabutyltin

Common Compatible SystemsSuitability
Aromatic hydrocarbon solvents (e.g., toluene, xylene)Highly Recommended – Excellent solubility and stability
Chlorinated solvents (e.g., dichloromethane, chloroform)Highly Recommended – No decomposition observed under ambient conditions
Polyol blends (e.g., polyester polyols)Recommended – Effective catalytic activity; monitor for potential side reactions above 180 °C
Aqueous systemsNot Suitable – Hydrolytically unstable; rapid degradation to dibutyltin oxide and butanol

Tetrabutyltin – Frequently Asked Questions (FAQ)

Q1: What is the CAS Number for Tetrabutyltin?

A: The CAS Registry Number for Tetrabutyltin is 1461-25-2.


Q2: What is the typical recommended dosage when used as a polyesterification catalyst?

A: Standard loading ranges from 0.05 to 0.2 wt% relative to total reactants; optimal dosage depends on acid value, temperature profile, and desired reaction kinetics—validation via small-scale trials is advised.


Q3: How does Tetrabutyltin compare to Dibutyltin Dilaurate (DBTDL) in catalytic performance?

A: Tetrabutyltin offers slower initiation and more controllable cure profiles than DBTDL, with lower acute toxicity but higher thermal stability—making it preferred for high-temperature, long-cycle processes where delayed catalysis is advantageous.


Q4: Is Tetrabutyltin compliant for use in food-contact polymers?

A: Tetrabutyltin is not permitted as a direct additive in EU or FDA food-contact polymers; residual limits apply only where it is an unavoidable trace impurity (< 1 ppm) in fully reacted, purified final products meeting specific migration thresholds (e.g., EU Regulation (EC) No 10/2011).


Q5: Can Tetrabutyltin migrate from cured resins into packaged goods?

A: Migration risk is low in fully cured, crosslinked systems; however, unreacted or hydrolytically degraded tetrabutyltin may release butanol and form more mobile dibutyltin species—strict process control, post-cure thermal treatment, and compliance testing per ISO 10993-12 are strongly recommended.



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