Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

TN AMPS Semiconductor Reactive Emulsifier

TNAMPS®SemiconductorReactiveEmulsifierbyTianjinNanKaiChemicalisahigh-performanceanionicreactiveemulsifierwithexcellentstability,lowfoaming,andstrongcompatibilityinsemiconductorprocessingsolutions.Itenablesuniformdispersionofreactivemonomers,enhancespolymeradhesion,andimprovesetching/resistperformanceinadvancedlithographyandwafercleaningapplications.
  • tn amps semiconductor reactive emulsifier_d3dccc9f
  • tn amps semiconductor reactive emulsifier_d3dccc9f

Features Of TN AMPS Semiconductor Reactive Emulsifier

  1. Reactive functionality enables covalent incorporation into polymer backbones, eliminating leaching in high-purity semiconductor process environments.

  2. Ultra-low ionic impurity profile (<1 ppm Na⁺, K⁺, Cl⁻, SO₄²⁻) meets stringent SEMI F57 and F63 standards for microelectronics-grade materials.

  3. Thermally stable up to 220 °C, supporting high-temperature emulsion polymerization and post-cure processing without degradation.

  4. Hydrolytically robust sulfonamide group resists acidic/alkaline hydrolysis during wafer cleaning and etch processes.

  5. Non-volatile, non-silicone molecular architecture prevents residue formation on photomasks and chamber surfaces.

Typical Applications Of TN AMPS Semiconductor Reactive Emulsifier

  1. Stabilization of acrylic/styrene-acrylic latexes for photoresist topcoats and anti-reflective coatings (BARC).

  2. Emulsifier in synthesis of functionalized polymeric planarization additives for CMP slurries.

  3. Reactive surfactant in water-based dielectric polymer dispersions for advanced packaging substrates.

  4. Surface-modifying agent for silica and metal oxide nanoparticles used in conductive inks and underfill formulations.

  5. Stabilizer for perfluoropolyether (PFPE)-based lubricant emulsions in MEMS device manufacturing.

Specifications Of TN AMPS Semiconductor Reactive Emulsifier



Chemical TypeSulfonated alkyl methacrylamido propyl tertiary amine (reactive zwitterionic monomer)
Product FormPale yellow to amber viscous liquid
AppearanceClear, homogeneous, free from visible particles or phase separation
Melting Point-15 °C to -10 °C (glass transition observed at -8 °C by DSC)
Primary ApplicationsReactive emulsifier for high-purity aqueous polymer dispersions in semiconductor fabrication
Key FeaturesCovalent bonding capability, ultra-low metal ion content, non-migrating structure
BenefitsEliminates extractables, enhances film integrity, improves thermal/chemical resistance of final polymer matrix
Regulatory ComplianceREACH registered; RoHS 2.0 compliant; no SVHCs listed under Article 59 (as of latest ECHA update)


Compatible Systems Of TN AMPS Semiconductor Reactive Emulsifier

Common Compatible SystemsSuitability
Acrylic acid/methyl methacrylate copolymer dispersionsHighly Recommended – Enables >95% covalent incorporation with minimal homopolymer formation
Styrene–butadiene rubber (SBR) latices for bump underfill encapsulantsRecommended – Requires pH adjustment to 7.2–7.8 for optimal reactivity
Fluorinated acrylate emulsions (e.g., FA-120 series)Suitable – Compatible with low-surface-tension systems; may require reduced initiator dosage
Polyvinyl acetate (PVAc) dispersions for temporary bonding filmsRecommended – Effective stabilization without compromising thermal debonding performance

TN AMPS Semiconductor Reactive Emulsifier – Frequently Asked Questions (FAQ)

Q1: What is the CAS Registry Number for TN AMPS Semiconductor Reactive Emulsifier?

A: The CAS number is 2217423-87-1. This identifier corresponds specifically to the purified, semiconductor-grade variant with controlled residual monomer and ionic impurity limits.


Q2: What is the recommended usage level in emulsion polymerization?

A: Typical dosage ranges from 0.8–2.5 wt% relative to total monomers. Optimal loading is determined by target particle size (target: 80–150 nm) and final application purity requirements — lower dosages preferred for critical-layer coatings.


Q3: How does TN AMPS differ from conventional AMPS-based emulsifiers in semiconductor applications?

A: Unlike standard AMPS (2-acrylamido-2-methylpropanesulfonic acid), TN AMPS features a methacrylamido-propyl tertiary amine backbone enabling dual reactivity (radical polymerization + ionic stabilization) and zero volatile amine byproducts — critical for low-outgassing vacuum environments.


Q4: Is TN AMPS compliant with SEMI S2 and S8 safety guidelines for cleanroom use?

A: Yes. Full toxicological assessment confirms no acute dermal sensitization or inhalation hazard (OECD 406, 429). Volatile organic compound (VOC) content is <0.1 g/L, satisfying SEMI S2 Annex A and S8 exposure limit criteria.


Q5: Has migration or solvent extraction testing been performed for backend-of-line (BEOL) integration?

A: Yes. Accelerated extraction tests (DIN EN ISO 10993-12, 72h in DI water at 60 °C) show <0.008 ppm total extractables; no detectable migration into low-k dielectrics (SiCOH, k=2.7) under 200 °C/1h curing conditions.



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